There is a relationship between the raising and lowering ladder operators and the creation and annihilation operators commonly used in quantum field theory which lies in representation theory. The creation operator ai† increments the number of particles in state i, while the corresponding annihilation operator ai decrements the number of particles in state i. This clearly satisfies the requirements of the above definition of a ladder operator: the incrementing or decrementing of the eigenvalue of another operator (in this case the particle number operator).
Confusion arises because the term ladder operator is typically used to describe an operator that acts to increment or decrement a quantum number describing the state of a system. To change the state of a particle with the creation/annihilation operators of QFT requires the use of both annihilation and creation operators. An annihilation operator is used to remove a particle from the initial state and a creation operator is used to add a particle to the final state.
The term "ladder operator" or "raising and lowering operators" is also sometimes used in mathematics, in the context of the theory of Lie algebras and in particular the affine Lie algebras. For example to describe the su(2) subalgebras, the root system and the highest weight modules can be constructed by means of the ladder operators.[1] In particular, the highest weight is annihilated by the raising operators; the rest of the positive root space is obtained by repeatedly applying the lowering operators (one set of ladder operators per subalgebra).
Suppose that two operators X and N have the commutation relation
for some scalar c. If is an eigenstate of N with eigenvalue equation
then the operator X acts on in such a way as to shift the eigenvalue by c:
In other words, if is an eigenstate of N with eigenvalue n, then is an eigenstate of N with eigenvalue n + c or is zero. The operator X is a raising operator for N if c is real and positive, and a lowering operator for N if c is real and negative.
A particular application of the ladder operator concept is found in the quantum-mechanical treatment of angular momentum. For a general angular momentum vectorJ with components Jx, Jy and Jz one defines the two ladder operators[3]
where i is the imaginary unit.
The commutation relation between the cartesian components of any angular momentum operator is given by
where εijk is the Levi-Civita symbol, and each of i, j and k can take any of the values x, y and z.
From this, the commutation relations among the ladder operators and Jz are obtained:
(technically, this is the Lie algebra of ).
The properties of the ladder operators can be determined by observing how they modify the action of the Jz operator on a given state:
Compare this result with
Thus, one concludes that is some scalar multiplied by :
This illustrates the defining feature of ladder operators in quantum mechanics: the incrementing (or decrementing) of a quantum number, thus mapping one quantum state onto another. This is the reason that they are often known as raising and lowering operators.
To obtain the values of α and β, first take the norm of each operator, recognizing that J+ and J− are a Hermitian conjugate pair ():
The product of the ladder operators can be expressed in terms of the commuting pair J2 and Jz:
Thus, one may express the values of |α|2 and |β|2 in terms of the eigenvalues of J2 and Jz:
The angular momentum algebra can often be simplified by recasting it in the spherical basis. Using the notation of spherical tensor operators, the "−1", "0" and "+1" components of J(1) ≡ J are given by[6]
From these definitions, it can be shown that the above scalar product can be expanded as
The significance of this expansion is that it clearly indicates which states are coupled by this term in the Hamiltonian, that is those with quantum numbers differing by mi = ±1 and mj = ∓1 only.
Another application of the ladder operator concept is found in the quantum-mechanical treatment of the harmonic oscillator. We can define the lowering and raising operators as
They provide a convenient means to extract energy eigenvalues without directly solving the system's differential equation.
There are two main approaches given in the literature using ladder operators, one using the Laplace–Runge–Lenz vector, another using factorization of the Hamiltonian.
Laplace–Runge–Lenz vector
Another application of the ladder operator concept is found in the quantum mechanical treatment of the electronic energy of hydrogen-like atoms and ions. The Laplace–Runge–Lenz vector commutes with the Hamiltonian for an inverse square spherically symmetric potential and can be used to determine ladder operators for this potential.[7][8]
We can define the lowering and raising operators (based on the classical Laplace–Runge–Lenz vector)
where is the angular momentum, is the linear momentum, is the reduced mass of the system, is the electronic charge, and is the atomic number of the nucleus.
Analogous to the angular momentum ladder operators, one has and .
The commutators needed to proceed are
and
Therefore,
and
so
where the "?" indicates a nascent quantum number which emerges from the discussion.
Given the Pauli equations[9][10] IV:
and III:
and starting with the equation
and expanding, one obtains (assuming is the maximum value of the angular momentum quantum number consonant with all other conditions)
which leads to the Rydberg formula
implying that , where is the traditional quantum number.
Factorization of the Hamiltonian
The Hamiltonian for a hydrogen-like potential can be written in spherical coordinates as
where , and the radial momentum
which is real and self-conjugate.
Suppose is an eigenvector of the Hamiltonian, where is the angular momentum, and represents the energy, so , and we may label the Hamiltonian as :
The factorization method was developed by Infeld and Hull[11] for differential equations. Newmarch and Golding[12] applied it to spherically symmetric potentials using operator notation.
Suppose we can find a factorization of the Hamiltonian by operators as
(1)
and
for scalars and . The vector may be evaluated in two different ways as
which can be re-arranged as
showing that is an eigenstate of with eigenvalue
If , then , and the states and
have the same energy.
For the hydrogenic atom, setting
with
a suitable equation for is
with
There is an upper bound to the ladder operator if the energy is negative (so
for some ), then if follows from equation (1) that
and can be identified with
Relation to group theory
Whenever there is degeneracy in a system, there is usually a related symmetry property and group. The degeneracy of the energy levels for the same value of but different angular momenta has been identified as the SO(4) symmetry of the spherically symmetric Coulomb potential.[13][14]
It can similarly be managed using the factorization method.
Factorization method
A suitable factorization is given by[12]
with
and
Then
and continuing this,
Now the Hamiltonian only has positive energy levels as can be seen from
This means that for some value of the series must terminate with
and then
This is decreasing in energy by unless for some value of . Identifying this value as gives
It then follows the so that
giving a recursion relation on with solution
There is degeneracy caused from angular momentum; there is additional degeneracy caused by the oscillator potential.
Consider the states
and apply the lowering operators :
giving the sequence
with the same energy but with decreasing by 2.
In addition to the angular momentum degeneracy, this gives a total degeneracy of [15]
Relation to group theory
The degeneracies of the 3D isotropic harmonic oscillator are related to the special unitary group SU(3)[15][16]
History
Many sources credit Paul Dirac with the invention of ladder operators.[17] Dirac's use of the ladder operators shows that the total angular momentum quantum number needs to be a non-negative half-integer multiple of ħ.
^David, C. W. (1966). "Ladder Operator Solution for the Hydrogen Atom Electronic Energy Levels". American Journal of Physics. 34 (10): 984–985. Bibcode:1966AmJPh..34..984D. doi:10.1119/1.1972354.
^
Lahiri, A.; Roy, P. K.; Bagchi, B. (1989). "Supersymmetry and the Ladder Operator Technique in Quantum Mechanics: The Radial Schrödinger Equation". Int. J. Theor. Phys. 28 (2): 183–189. Bibcode:1989IJTP...28..183L. doi:10.1007/BF00669809. S2CID123255435.
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