It has been investigated at CERN to measure its lifetime. The Dimeson Relativistic Atomic Complex (DIRAC) experiment at the Proton Synchrotron was able to detect 21227 atomic pairs from a total of 1.5×109 events, which allows the pionium lifetime to be determined to within statistical errors of 9%.[1]
In 2006, the NA48/2 collaboration at CERN published an evidence for pionium production and decay in decays of charged kaons, studying mass spectra of daughter pion pairs in the events with three pions in the final state K± → π±(ππ)atom → π±π0π0.[2] This was followed by a precision measurement of the S-wave pion scattering length, published by the collaboration in 2009.[3]
The results of the above experiments will provide crucial tests of low-energy QCD predictions.[4]