Ytterbium monotelluride

Ytterbium monotelluride
Identifiers
CAS Number	12125-58-5 ;
3D model (JSmol)	Interactive image;
ECHA InfoCard	100.031.983
EC Number	235-194-8;
PubChem CID	82928;
CompTox Dashboard (EPA)	DTXSID701311611 ;
	InChI InChI=1S/Te.Yb Key: WNXKQTAPAWGMPP-UHFFFAOYSA-N;
	SMILES [Te].[Yb];
Properties
Chemical formula	TeYb
Molar mass	300.65 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Ytterbium monotelluride is an inorganic compound, one of the tellurides of ytterbium, with the chemical formula YbTe.

Preparation

Ytterbium monotelluride can be produced by the high-temperature reduction reaction of ytterbium(III) telluride (Yb₂Te₃),^[1] or by the reaction of ytterbium(III) chloride, tellurium and hydrogen:^[2]

YbCl₃ + H₂ → YbCl₂ + 2 HCl

YbCl₂ + H₂ + Te → YbTe + 2 HCl

The thermal decomposition of [(py)₂Yb(μ-η²-η²-PhNNPh)(TePh)]₂·₂py will also produce ytterbium monotelluride, but at the same time, ytterbium(III) nitride will be produced.^[3]

References

^ Senff, Heinz; Klemm, Wilhelm. Measurements on bivalent and quadrivalent compounds of the rare earths. IX. The selenides and tellurides of bivalent ytterbium. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1939. 242: 92-96.
^ Obolonchik, V. A.; Yanaki, A. A. Synthesis of some rare-earth metal tellurides. Khal'kogenidy, 1970. 2: 141-148. CODEN D8MMYC.
^ Kornienko, Anna; Freedman, Deborah; Emge, Thomas J.; Brennan, John G. (2001-01-01). "Heteroleptic Lanthanide Compounds with Chalcogenolate Ligands: Reduction of PhNNPh/PhEEPh (E = Se or Te) Mixtures with Ln (Ln = Ho, Er, Tm, Yb). Thermolysis Can Give LnN or LnE". Inorganic Chemistry. 40 (1): 140–145. doi:10.1021/ic000499y. ISSN 0020-1669. PMID 11195372. Archived from the original on 2023-05-10. Retrieved 2023-06-13.

Ziya S. Aliev, Gulnara I. Ibadova, Jean-Claude Tedenac, Mahammad B. Babanly (Jul 2014). "Study of the YbTe–SnTe–Sb2Te3 quasi-ternary system". Journal of Alloys and Compounds. 602: 248–254. doi:10.1016/j.jallcom.2014.03.036. Archived from the original on 2018-06-09. Retrieved 2023-06-13.{{cite journal}}: CS1 maint: multiple names: authors list (link)
Siron, Martin; Andriuc, Oxana; Persson, Kristin A. (2022-08-11). "Data-Driven Investigation of Tellurium-Containing Semiconductors for CO 2 Reduction: Trends in Adsorption and Scaling Relations". The Journal of Physical Chemistry C. 126 (31): 13224–13236. doi:10.1021/acs.jpcc.2c04810. ISSN 1932-7447. PMC 9377373. PMID 35983310.

[1] Senff, Heinz; Klemm, Wilhelm. Measurements on bivalent and quadrivalent compounds of the rare earths. IX. The selenides and tellurides of bivalent ytterbium. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1939. 242: 92-96.

[2] Obolonchik, V. A.; Yanaki, A. A. Synthesis of some rare-earth metal tellurides. Khal'kogenidy, 1970. 2: 141-148. CODEN D8MMYC.

[3] Kornienko, Anna; Freedman, Deborah; Emge, Thomas J.; Brennan, John G. (2001-01-01). "Heteroleptic Lanthanide Compounds with Chalcogenolate Ligands: Reduction of PhNNPh/PhEEPh (E = Se or Te) Mixtures with Ln (Ln = Ho, Er, Tm, Yb). Thermolysis Can Give LnN or LnE". Inorganic Chemistry. 40 (1): 140–145. doi:10.1021/ic000499y. ISSN 0020-1669. PMID 11195372. Archived from the original on 2023-05-10. Retrieved 2023-06-13.

[1]

[2]

[3]

Ytterbium monotelluride

Preparation

References

Further reading